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Gayan B. Wijeratne, Ph.D.
Gayan B. Wijeratne, Ph.D.
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Synthetic Fe/Cu complexes: toward understanding heme-copper oxidase structure and function
SM Adam, GB Wijeratne, PJ Rogler, DE Diaz, DA Quist, JJ Liu, KD Karlin
Chemical reviews 118 (22), 10840-11022, 2018
1752018
Saturation Kinetics in Phenolic O–H Bond Oxidation by a Mononuclear Mn (III)–OH Complex Derived from Dioxygen
GB Wijeratne, B Corzine, VW Day, TA Jackson
Inorganic Chemistry 53 (14), 7622-7634, 2014
972014
Copper(I)/NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex: Redox Reversal Giving Copper(I)/NO(g) Disproportionation
GB Wijeratne, S Hematian, MA Siegler, KD Karlin
Journal of the American Chemical Society 139 (38), 13276-13279, 2017
452017
Steric and electronic influence on proton-coupled electron-transfer reactivity of a mononuclear Mn (III)-hydroxo complex
DB Rice, GB Wijeratne, AD Burr, JD Parham, VW Day, TA Jackson
Inorganic Chemistry 55 (16), 8110-8120, 2016
452016
Electronic structure and reactivity of a well-defined mononuclear complex of Ti (II)
GB Wijeratne, EM Zolnhofer, S Fortier, LN Grant, PJ Carroll, CH Chen, ...
Inorganic Chemistry 54 (21), 10380-10397, 2015
402015
Modeling tryptophan/indoleamine 2, 3-dioxygenase with heme superoxide mimics: is ferryl the key intermediate?
P Mondal, GB Wijeratne
Journal of the American Chemical Society 142 (4), 1846-1856, 2019
272019
Vanadocene de Novo: Spectroscopic and Computational Analysis of Bis(η5-cyclopentadienyl)vanadium(II)
TA Jackson, J Krzystek, A Ozarowski, GB Wijeratne, BF Wicker, ...
Organometallics 31 (23), 8265-8274, 2012
262012
O–H bond oxidation by a monomeric Mn III–OMe complex
GB Wijeratne, VW Day, TA Jackson
Dalton Transactions 44 (7), 3295-3306, 2015
242015
Geometric and electronic structure of a peroxomanganese (iii) complex supported by a scorpionate ligand
HE Colmer, RA Geiger, DF Leto, GB Wijeratne, VW Day, TA Jackson
Dalton Transactions 43 (48), 17949-17963, 2014
232014
Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release
GB Wijeratne, M Bhadra, MA Siegler, KD Karlin
Journal of the American Chemical Society 141 (45), 17962-17967, 2019
192019
Steric and electronic influences on the structures of peroxomanganese (III) complexes supported by tetradentate ligands
RA Geiger, GB Wijeratne, VW Day, TA Jackson
European Journal of Inorganic Chemistry 2012 (10), 1598-1608, 2012
192012
Spectroscopic and Structural Characterization of Mn (III)-Alkylperoxo Complexes Supported by Pentadentate Amide-Containing Ligands
JD Parham, GB Wijeratne, DB Rice, TA Jackson
Inorganic Chemistry 57 (5), 2489-2502, 2018
182018
Proton-coupled electron transfer reactivities of electronically divergent heme superoxide intermediates: a kinetic, thermodynamic, and theoretical study
P Mondal, I Ishigami, EF Gérard, C Lim, SR Yeh, SP de Visser, ...
Chemical Science 12 (25), 8872-8883, 2021
132021
Electronic structure and magnetic properties of a titanium (II) coordination complex
EM Zolnhofer, GB Wijeratne, TA Jackson, S Fortier, FW Heinemann, ...
Inorganic Chemistry 59 (9), 6187-6201, 2020
132020
Steric control of dioxygen activation pathways for Mn II complexes supported by pentadentate, amide-containing ligands
JD Parham, GB Wijeratne, JR Mayfield, TA Jackson
Dalton Transactions 48 (34), 13034-13045, 2019
132019
Mn K-edge X-ray absorption studies of mononuclear Mn (III)–hydroxo complexes
DB Rice, GB Wijeratne, TA Jackson
JBIC Journal of Biological Inorganic Chemistry 22, 1281-1293, 2017
122017
Isolation and characterization of a peroxo manganese (III) dioxygen reaction intermediate using cryogenic ion vibrational predissociation spectroscopy
AB Wolk, CM Leavitt, JA Fournier, MZ Kamrath, GB Wijeratne, TA Jackson, ...
International Journal of Mass Spectrometry 354, 33-38, 2013
122013
Following nature’s footprint: mimicking the high-valent heme-oxo mediated indole monooxygenation reaction landscape of heme enzymes
P Mondal, S Rajapakse, GB Wijeratne
Journal of the American Chemical Society 144 (9), 3843-3854, 2022
112022
Mn III-Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity
MC Denler, GB Wijeratne, DB Rice, HE Colmer, VW Day, TA Jackson
Dalton Transactions 47 (38), 13442-13458, 2018
112018
The Role of Heme Peroxo Oxidants in the Rational Mechanistic Modeling of Nitric Oxide Synthase: Characterization of Key Intermediates and Elucidation of the Mechanism
P Mondal, I Ishigami, SR Yeh, GB Wijeratne
Angewandte Chemie International Edition 61 (48), e202211521, 2022
22022
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